
Keep me posted with your results so that I can help you further.
Put the computer back to internet connection and test. Type appwiz.cpl in the run textbox and hit enter to open the Programs and Features window.
Since windows live essentials is what drives windows live mail, repairing the utility will repair corrupt and unreadable data in WLM.
Then delete the photo email that caused this problem. Method 4: Repair Windows Live Essentials. There you shall see Outbox, click to open it. When Windows Live Mail is now disconnected from the internet, click on the Newsgroups button at the very bottom of the Windows Live Mail window. Another way is to set it to Work Offline by clicking on Work Offline button at the far right corner of the Live Mail screen. If it freezes immediately after opening, you need to temporarily disconnect that computer from the internet by turning off the wifi or unplugging the ethernet cable. However, Windows Live Mail normally has no Outbox. In order to fix this problem, you need to delete those unsent photo emails from your Outbox. Thus, it will cause a problem specially for non Microsoft email account and those without Skydrive (the Microsoft cloud) access. I truly believe that the photo email that you were trying to send was the cause of this problem as photo emails requires you to have a cloud account with hotmail or so that the photos are sent there and made accessible for photo emails.